Adsorption of Polylysine, Poly(glutamic) acid and their Block Copolymers on Polystyrene and on Carbon Nanotubes
نویسنده
چکیده
A better understanding of protein behavior at solid-liquid interfaces is important to improve our knowledge of various natural and synthetic processes. A few examples where protein adsorption at a solid-liquid interface may play an important role are found in: blood coagulation, artificial kidney failure, biomedical microdevices, self-assembling microelectromechanical systems (MEMS), protein based microarrays, design and fabrication of biosensors/ biomaterials, filtration systems in bioseparation processes, etc. The structure of adsorbed proteins, its dependence on sorbent and solution properties, and the contribution of protein structural rearrangements to the driving force for adsorption are the most poorly understood aspects of the protein adsorption processes
منابع مشابه
Grafting of alkoxyamine end-capped (co)polymers onto multi-walled carbon nanotubes
Multi-walled carbon nanotubes (MWNTs) have been successfully modified by polystyrene, poly( caprolactone), and their block copolymers by addition reaction of the alkoxyamine-terminated precursors. Polymer-modified MWNTs are easily dispersed in good solvents for the grafted polymer, such as toluene and THF. This observation has been confirmed by TEM analysis. The grafting ratio of polystyrene ch...
متن کاملEffect of Acid Treatment of Carbon Nanotubes on Their Adsorption Capacities of Benzene and Toluene
Toluene and benzene were eliminated using multi-walled carbon nanotubes (MWCNTs). In order to investigate influence of acid treatment on the MWCNTs adsorption capacities, the MWCNTs were functionalized by nitric acid (10 M) under reflux conditions for 2 h. Fourier transform infrared (FTIR) and Raman spectroscopy were employed to confirm the formation of functional groups on the nanotubes su...
متن کاملControlled Dispersion of Carbon Nanotubes Wrapped in Amphiphilic Block Copolymers: Elaboration of Polymer Nanocomposite
In this work, we aim to prepare polymer nanocomposites by the dispersion of multiwall carbon nanotube (MWCNT) in aqueous solution using amphiphilic block copolymers. First, we report our success in wrapping MWCNT with amphiphilic block copolymers in aqueous solution. We selected poly(ethylene oxide) (PEO) as the hydrophilic block because of its strong affinity for water and its easiness synthes...
متن کاملGenerating suspended single-walled carbon nanotubes across a large surface area via patterning self-assembled catalyst-containing block copolymer thin films.
Using self-assembled block copolymers as templates, catalytically active nanostructures with controlled size and space have been produced. A self-assembled polystyrene-b-polyferrocenylsilane thin film and monolayer of surface micelles of cobalt-complexed polystyrene-b-poly(2-vinylpyridine) are fully compatible with novolac-based conventional photoresists. Combining bottom-up self-assembly of ca...
متن کاملA Study of Effects of Different Surface Modifications of MWCNTs on their Adsorption Capacity of Benzene and Toluene
Multi-Walled Carbon Nanotubes (MWCNTs) surfaces were serially modified by the annealing treatment under Helium flow at 1000oC, the nitric acid treatment and again the annealing treatment under same conditions and their maximum adsorption capacities for benzene and toluene were measured and analyzed. The unmodified and modified MWCNTs werecharacterized by Fourier Tr...
متن کامل